General Information
    • ISSN: 2010-0221
    • Frequency: Bimonthly
    • DOI: 10.18178/IJCEA
    • Editor-in-Chief: Dr. Eldin W. C. Lim
    • Executive Editor: Mr. Ron C. Wu
    • Abstracting/ Indexing: Chemical Abstracts Services (CAS), Ulrich's Periodicals Directory, CABI, DOAJ, Electronic Journals Library, Google Scholar, Engineering & Technology Digital Library, ProQuest, and Crossref
    • E-mail: ijcea@ejournal.net
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Editor-in-chief
Dr. Eldin W. C. Lim
Dept. of Chemical and Biomolecular Engineering,
National University of Singapore, Singapore
IJCEA 2013 Vol.4(3): 96-100 ISSN: 2010-0221
DOI: 10.7763/IJCEA.2013.V4.271

Surface Tension of Ionic Liquids Analogues Using the QSPR Correlation

F. S. Mjalli, K. Shahbaz, M. A. Hashim, and I. M. AlNashef
Abstract—Deep eutectic solvents (DESs) are mixture complexes being introduced in many applications due to their favorable physicochemical characteristics. However, due to the lack of experimental data, prediction of their physical properties is challenging. One of the important physical properties that provides considerable insight of the molecular influence on intensity of interactions in the mixture is the surface tension. In this work, the QSPR prediction method was employed to predict the DESs surface tension. The parachors of selected DESs based on ammonium and phosphunium salts were determined experimentally and also calculated from the molecular structure of their constituting components using available parachor contribution data for neutral compounds. The results showed that the calculated and experimental parachors of DESs were notably comparable and the parachor contribution data developed for neutral compounds can be successfully utilized for DESs. The calculated parachors were employed to predict the surface tension using their experimental densities values.

Index Terms—Surface tension, deep eutectic solvents, prediction.

F. S. Mjalli is with Petroleum and Chemical Engineering Department, Sultan Qaboos University, Oman (e-mail: farouqsm@yahoo.com).
K. Shahbaz is with the School of Engineering, Taylor’s University, 47500 Selangor, Malaysia (e-mail: shahbaz.kaveh@gmail.com).
M. A. Hashim is with University of Malaya, Chemical Engineering Department, Kuala Lumpur, Malaysia (e-mail: alihashim@um.edu.my).
I. M. AlNashef is with King Saud University, Chemical Engineering Department, Riyadh, Saudi Arabia (e-mail: alnashef@ksu.edu.sa).

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Cite:F. S. Mjalli, K. Shahbaz, M. A. Hashim, and I. M. AlNashef, "Surface Tension of Ionic Liquids Analogues Using the QSPR Correlation," International Journal of Chemical Engineering and Applications vol. 4, no. 3, pp. 96-100, 2013.

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