General Information
    • ISSN: 2010-0221
    • Frequency: Bimonthly
    • DOI: 10.18178/IJCEA
    • Editor-in-Chief: Prof. Dr. Shen-Ming Chen
    • Executive Editor: Mr. Ron C. Wu
    • Abstracting/ Indexing: Chemical Abstracts Services (CAS), Ulrich's Periodicals Directory, CABI, DOAJ, Electronic Journals Library, Google Scholar, ProQuest, and Crossref
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Editor-in-chief
Prof. Dr. Shen-Ming Chen
National Taipei University of Technology, Taiwan
 

IJCEA 2016 Vol.7(3): 213-216 ISSN: 2010-0221
DOI: 10.7763/IJCEA.2016.V7.575

Microwave Assisted Solvent Free Synthesis of Disulfides with Tributylammonium Halochromates(VI), (C4H9)3NH+[CrO3X]-, (X=F, Cl)

Mohammad Kazem Mohammadi and Parya Nasehi
Abstract—Oxidative coupling of thiols to the corresponding symmetrical disulfides were performed in the presence of silica gel supported tributylammonium fluorochromate(VI), (TBAFC), and tributylammonium chlorochromate(VI), (TBACC). TriBAFC and TriBACC are versatile reagents for the effective and selective oxidation of organic substrates, in particular of thiol, in solution and under microwave conditions. Considerable improvements are observed in the presence of the microwave and making the work-up much more convenient.

Index Terms—Halochromates, microwave, thiol, disulfide.

Mohammad Kazem Mohammadi, Parya Nasehi are with Department of Chemistry, Ahvaz Branch , Islamic Azad University, Ahvaz, Iran (e-mail: mohammadi@iauahvaz.ac.ir).

[PDF]

Cite: Mohammad Kazem Mohammadi and Parya Nasehi, "Microwave Assisted Solvent Free Synthesis of Disulfides with Tributylammonium Halochromates(VI), (C4H9)3NH+[CrO3X]-, (X=F, Cl)," International Journal of Chemical Engineering and Applications vol. 7, no. 3, pp. 213-216, 2016.

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