General Information
    • ISSN: 2010-0221 (Print)
    • Abbreviated Title: Int. J. Chem. Eng. Appl.
    • Frequency: Quarterly
    • DOI: 10.18178/IJCEA
    • Editor-in-Chief: Prof. Dr. Shen-Ming Chen
    • Executive Editor: Jennifer X. Zeng
    • Abstracting/ Indexing: Chemical Abstracts Services (CAS), Ulrich's Periodicals Directory, CABI, Electronic Journals Library, Google Scholar, ProQuest,  Crossref, EBSCO, CNKI.
    • Email: ijcea@ejournal.net
  • Apr 25, 2022 News! Vol.13, No.2 has been published with online version.   [Click]
  • Jan 26, 2022 News! Vol.13, No.1 has been published with online version.   [Click]
Editor-in-chief
Prof. Dr. Shen-Ming Chen
National Taipei University of Technology, Taiwan
 

IJCEA 2016 Vol.7(1): 52-55 ISSN: 2010-0221
DOI: 10.7763/IJCEA.2016.V7.541

Synthesis and Visible-Light Photochromism of a Donor-Acceptor Type of Dimethyl 2,3-bis(arylethynyl)fumarate

Ryota Sakamoto
Abstract—Herein, the author synthesized a donor-acceptor type of photochromic dimethyl 2,3-bis(arylethynyl)fumarate, (E)-2, where ferrocene and 4-nitrobenzene were employed as donor and acceptor arenes, respectively. Compared to parent dimethyl 2,3-bis(ferrocenylethynyl)fumarate, (E)-2 enjoyed more profound donor-acceptor interaction, leading to a red-shifted intramolecular charge transfer band. (E)-2 underwent visible-light photochromism upon excitation with the intramolecular charge transfer band.

Index Terms—Photochromism, ferrocene, donor-acceptor interaction.

Ryota Sakamoto is with the University of Tokyo, Japan (e-mail: sakamoto@chem.s.u-tokyo.ac.jp).

[PDF]

Cite: Ryota Sakamoto, "Synthesis and Visible-Light Photochromism of a Donor-Acceptor Type of Dimethyl 2,3-bis(arylethynyl)fumarate," International Journal of Chemical Engineering and Applications vol. 7, no. 1, pp. 52-55, 2016.

Copyright © 2008-2022. International Journal of Chemical Engineering and Applications. All rights reserved
E-mail: ijcea@ejournal.net